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Influence of Irradiation and Hydrolysis on Mechanical Properties and Crystallization in Selected Copolymers

The first part of the thesis investigates the effects of electron beam irradiation on polymeric structures. Particular attention is given to the influence of varying irradiation dose on cross-linking efficiency, crystallinity (??), and mechanical behavior. Experimental results demonstrate how irradiation modifies the material’s resistance to deformation and enhances its thermal stability at elevated temperatures. The relationship between copolymer composition and the efficiency of cross-linking reactions is explored in detail, providing insights into the optimization of material performance through structural control. The second part focuses on the hydrolytic degradation of the biodegradable copolyester poly(butylene succinate-co-adipate) (PBSA) under controlled laboratory conditions. The study evaluates the impact of hydrolysis on molecular weight, molecular weight distribution (??????), and thermal properties such as melting (????) and glass transition temperatures �????�. Emphasis is placed on the changes in crystallization behavior and morphological evolution of the polymer, as observed at the microscopic level. These findings contribute to a deeper understanding of the long-term stability and environmental degradability of polymeric materials in various conditions. This doctoral thesis summary presents a comprehensive and integrated analysis of the effects of electron beam irradiation and hydrolytic degradation on the physicochemical and mechanical properties of polymeric materials. The results contribute fundamentally to the design of advanced polymers with tunable performance parameters and provide a scientific basis for predicting their durability and functional behavior under demanding service conditions.
ISBN:978-80-7678-388-1
EAN:9788076783881
Počet stran 68 stran
Datum vydání 30. 12. 2025
Pořadí vydání První
Jazyk anglický
Vazba e-kniha - pdf
Autor: Anna Švarcová
Nakladatelství Univerzita Tomáše Bati ve Zlíně
Tématická skupina 999 - nezařazeno
Neprodejná publikace. Publikaci je možné poptávat zde: Volně dostupné na http://hdl.handle.net/10563/59079
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