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Polymeric blends based on linear and branched polypropylene: crystallization, polymorphism and properties

The objective of the presented doctoral thesis aims to investigate the morphology of linear and long-chain branched polypropylene, with a particular focus on identifying optimal conditions for controlling the phase structure. This includes exploring the influence of process parameters and chemical composition on the phase formation and structure. Special attention is dedicated to the effect of incorporating long branches of long-chain branched polypropylene into the linear polypropylene. Key findings of the study reveal that long-chain branched polypropylene can enhance the crystallization process, outperforming traditional nucleating agents. Long-chain branched polypropylene not only reduces haze and speeds up crystallization but also promotes the formation of finer crystalline structures in polypropylene blends, even at low concentrations. The research further identifies long-chain branched polypropylene as a potential alternative to conventional nucleating agents, especially in high-temperature processing applications. Additionally, the thesis explores annealing as a method for improving the crystalline phases and mechanical properties of polypropylene. It also highlights the transformation of the β-phase into the α-phase as an effective method of improving material performance.
ISBN:978-80-7678-325-6
EAN:9788076783256
Počet stran 44 stran
Datum vydání 19. 03. 2025
Pořadí vydání První
Jazyk anglický
Vazba e-kniha - ostatní
Autor: Soňa Zenzingerová
Nakladatelství Univerzita Tomáše Bati ve Zlíně
Tématická skupina 999 - nezařazeno
Neprodejná publikace. Publikaci je možné poptávat zde: Volně dostupné na http://hdl.handle.net/10563/56827
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